1. LDLC vs Na'Vi
Those 2 teams are hard to predict, because of the style of the players and because LDLC and Na'Vi played against eachother 5+ times.
3 won by LDLC, 1 draw and 1 won by Na'Vi.
Althought Na'Vi is a better team in the last few days and their players are motivated to win.
My choice here is Na'Vi and my personal odds are Na'Vi 60% - LDLC 40%
Na'Vi

2. Loser of LDLC/NaVi vs CW
CW got very low chances, but the odds in ♥♥♥♥♥♥♥♥♥♥ are 80 to 20 (my odds, too), so there is no point in betting on that match.
Skip

3. Fnatic vs VP
Fnatic and VP met many times too, almost every time the odds are 50-50.
Last 5 times the team met the results were 4 draws and 1 win for VP.
My personal choice is Fnatic, because of their new lineup, If you are not sure, better skip, odds are 50% - 50%
Fnatic or skip

4. Loser of Fnatic/VP vs IBP
Gonna be thuff match, but I will put my bet on Fnatic/VP, because the loser of the previous match will have warm up and bigger motivation, odds are like 60% - 40 %
Fnatic/VP

5. Cloud9 vs Dignitas
50% - 50 %
I will put small bet on Dignitas, but I can't say they will win.
Skip or choose by yourself

6. Loser of Cloud9/Dignitas vs Titan
Yesterday Titan lost by Cloud9 and Dignitas have beaten Titan many times. I will go for loser.
Loser or skip.

You don't need to listen what I say, I am just saying where and why I put my bet.

Some rules about the pro teams:
Here there is 1 special rule: Pro teams are hard to predict, there are always comebacks, DDOS problems, Net problems and lazy/motivated players. Often time one of the best csgo teams loose from one of the weekest.
Some times big teams pass a match (don't play serious) and keep their tactics/skills for a incoming tournament.
It is good to check on HLTV about such things.
Stats are important too, but not something you can really trust.
It is important if the match is online or LAN too.